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Process Data set: nickel–cobalt saggarsrecycling and utilizing (en) en zh

Key Data Set Information
Location CN
Reference year 2018
Name
nickel–cobalt saggarsrecycling and utilizing
Use advice for data set Users of this data set should ensure that the data is applied specifically to scenarios involving the recycling and recovery of nickel, cobalt, and manganese from lithium battery casings. It is important to account for the use phase behavior of recycled materials and to apply the data accordingly when modeling life cycle assessments. The emergy values given in the provided data must be handled with care, incorporating Liu and Yang's 'Energy Analysis Theory and Practice' for methodology reference. This data set is based on the functional unit of 1 kWh energy equivalence, with the calculation basis being GEB2016 (12.0 × 1024 sej). Users should ensure that their methodologies align with this basis when interpreting and integrating the data.
Technical purpose of product or process The technology for recycling and utilizing nickel-cobalt saggars described refers to the extraction of valuable materials such as nickel, cobalt, and manganese precursors, as well as lithium carbonate from recycled waste sagger materials. This process is designed for the recovery of these critical materials from spent lithium battery casings. The secondary products produced, including alum and potassium sulphate, are typically utilized in various industrial applications, such as in the production of alum-based products and fertilizers.
Classification
Class name : Hierarchy level
  • ILCD: End-of-life treatment / Material recycling
General comment on data set Utilizing the recycled waste sagger, nickel, cobalt and manganese precursors are extracted, as well as lithium carbonate and other products, and by-products such as alum and potassium sulphate are produced through the processes of physical separation, reductive leaching, tandem separation, evaporation and crystallization, and purification.
Copyright No
Owner of data set
Quantitative reference
Reference flow(s)
Functional Unit calculation basis is GEB2016 (12.0 × 1024 sej)
Technological representativeness
Technology description including background system In the physical separation process, the inner surface of recycled waste saggars which contain multiple metals is first mechanically ground into powder. Then, this powder is separated from the saggars and enters the reduction and leaching process. The remain.ing saggars are used as a base aggregate for ceramic production, In the reduction andleaching process, the metal elements, including nickel, cobalt, lithium, and manganeseare immersed in an acid solution. The acid solution enters the cascade separation processto obtain primary products of important elements. The produced acid leaching residuesare treated as solid waste by qualified institutions for further processing. The acid leach.ing solution enters the cascade separation step, a crude nickel-cobalt-manganese ternaryprecursor product is generated that goes to the purification step, and alum, aluminumhydroxide, and magnesium hydroxide are generated for sale. The remaining filtrate entersthe crystallization step for further refinement, In the crystallization process, the filtrateis evaporated and crystallized to produce a crude product of lithium carbonate, and itproduces potassium sulfate, The crude lithium carbonate enters the purification processand the potassium sulfate is for direct sale. The remaining concentrated mother liquorenters the cascade separation process for the further extraction of metal elements. In thepurification process, the nickel, cobalt, and manganese precursors and lithium carbonateare purified to battery quality and sold as the main products.
Flow diagram(s) or picture(s)
  • PNfCbOpCdoR2DCxAlTAcsSa4n4b.png Image
LCI method and allocation
Type of data set Unit process, black box
Deviation from LCI method principle / explanations None
Deviation from modelling constants / explanations None
Data sources, treatment and representativeness
Deviation from data cut-off and completeness principles / explanations None
Data selection and combination principles The data used in this article are mainly derived from the analysis data of the results of the pilot test conducted by the Institute of Process Engineering of the Chinese Academy of Sciences with a company in Hunan Province, China, including physical separation, reduction and leaching, cascade separation, crystallization, and purification. The emergy values of the various raw materials and emissions are from the Appendix of “Energy Analysis Theory and Practice” by Liu and Yang
Deviation from data selection and combination principles / explanations None
Deviation from data treatment and extrapolations principles / explanations None
Data source(s) used for this data set
Completeness
Completeness of product model No statement
Validation
Type of review
Dependent internal review
Reviewer name and institution
Data generator
Data set generator / modeller
Data entry by
Time stamp (last saved) 2024-04-10T23:47:53+08:00
Publication and ownership
UUID f8812b3b-aeba-4775-bb85-323da6d872d6
Date of last revision 2024-05-13T14:56:02.698422+08:00
Data set version 01.00.005
Permanent data set URI https://lcadata.tiangong.world/showProcess.xhtml?uuid=f8812b3b-aeba-4775-bb85-323da6d872d6&version=01.00.000&stock=TianGong
Owner of data set
Copyright No
License type Free of charge for all users and uses

Inputs

Type of flow Classification Flow Location Mean amount Resulting amount Minimum amount Maximum amount
Elementary flow Resources / Resources from water / Renewable material resources from water 149.2 m3149.2 m3
Product flow Energy carriers and technologies / Electricity 29.7 MJ29.7 MJ
Product flow
End-of-life treatment / Material recycling 1000.0 kg1000.0 kg
General comment Ni-Co-containing saggars
Product flow
Materials production / Inorganic chemicals 216.0 kg216.0 kg
General comment Sulfuric acid
Product flow
End-of-life treatment / Waste water treatment 160.0 kg160.0 kg
General comment Leaching residue washing water
Elementary flow Resources / Resources from water / Renewable material resources from water 216.0 m3216.0 m3
Product flow Energy carriers and technologies / Electricity 17.82 MJ17.82 MJ
Product flow Energy carriers and technologies / Heat and steam 10.0 MJ10.0 MJ
Elementary flow
Resources / Resources from ground / Non-renewable element resources from ground 55.6 kg55.6 kg
General comment Potassium hydroxide
Elementary flow Resources / Resources from water / Renewable material resources from water 85.6 m385.6 m3
Product flow
Materials production / Other materials 59.6 kg59.6 kg
General comment Concentrated mother liquor
Elementary flow
Resources / Resources from ground / Non-renewable element resources from ground 20.0 kg20.0 kg
General comment Potassium sulfate
Product flow Energy carriers and technologies / Electricity 3.96 MJ3.96 MJ
Product flow Energy carriers and technologies / Heat and steam 12.0 MJ12.0 MJ
Product flow
Materials production / Inorganic chemicals 66.0 kg66.0 kg
General comment Potassium carbonate
Elementary flow Resources / Resources from water / Renewable material resources from water 96.4 m396.4 m3
Product flow Energy carriers and technologies / Electricity 59.4 MJ59.4 MJ
Product flow
Energy carriers and technologies / Heat and steam 198.0 MJ198.0 MJ
General comment Steam
Product flow
Materials production / Other materials 5.8 kg5.8 kg
General comment Crude Ni-Co-Mn precursor
Product flow
Materials production / Inorganic chemicals 35.2 kg35.2 kg
General comment Crude lithium carbonate
Product flow
Materials production / Inorganic chemicals 10.0 kg10.0 kg
General comment Sulfuric acid(98%)
Elementary flow
Resources / Resources from air / Renewable material resources from air 11.0 kg11.0 kg
General comment The original text does not distinguish between bio and fossil, and according to experts, it is fossil here
Elementary flow
Resources / Resources from water / Renewable material resources from water 16.0 m316.0 m3
General comment Pure water
Elementary flow
Emissions / Emissions to water / Emissions to water, unspecified 9.0 kg9.0 kg
General comment 25%Ammonia
Product flow Materials production / Inorganic chemicals 6.0 kg6.0 kg
Product flow Energy carriers and technologies / Electricity 7.2 MJ7.2 MJ
Product flow Energy carriers and technologies / Heat and steam 10.0 MJ10.0 MJ
Product flow
Materials production / Other materials 171.4 kg171.4 kg
General comment Polishing powder with 30% water content
Product flow
Materials production / Inorganic chemicals 647.0 kg647.0 kg
General comment Acidic leaching liquor
Product flow
Materials production / Raw materials 693.2 kg693.2 kg
General comment Contains potassium ion and lithium ion filter liquor

Outputs

Type of flow Classification Flow Location Mean amount Resulting amount Minimum amount Maximum amount
Elementary flow
Resources / Resources from ground / Non-renewable material resources from ground 977.8 kg977.8 kg
General comment Ceramic aggregate
Product flow
Materials production / Other materials 171.4 kg171.4 kg
General comment Polishing powder with 30% water content
Product flow
Materials production / Inorganic chemicals 647.0 kg647.0 kg
General comment Acidic leaching liquor
Product flow
Wastes / Production residues 128.4 kg128.4 kg
General comment Leaching residue
Product flow
Materials production / Inorganic chemicals 166.2 kg166.2 kg
General comment Alum
Product flow
Materials production / Other materials 5.8 kg5.8 kg
General comment Ni-Co-Mn precursor
Product flow
Materials production / Raw materials 693.2 kg693.2 kg
General comment Contains potassium ion and lithium ion filter liquor
Product flow
Materials production / Inorganic chemicals 1.4 kg1.4 kg
General comment Magnesium hydroxide
Product flow
Materials production / Inorganic chemicals 1.2 kg1.2 kg
General comment Aluminum hydroxide
Elementary flow
Resources / Resources from ground / Non-renewable material resources from ground 104.0 kg104.0 kg
General comment Potassium sulfate
Product flow
Materials production / Other materials 59.6 kg59.6 kg
General comment Concentrated mother liquor
Product flow
Materials production / Water 656.8 kg656.8 kg
General comment Condensed water
Product flow
Materials production / Inorganic chemicals 35.2 kg35.2 kg
General comment Crude lithium carbonate
Product flow
Materials production / Other materials 5.0 kg5.0 kg
General comment Ni-Co-Mn precursor
Product flow
Materials production / Other materials 28.2 kg28.2 kg
General comment Ni-Co-Mn precursor
Product flow
Wastes / Production residues 1.8 kg1.8 kg
General comment Calcium Magnesium slag
Product flow End-of-life treatment / Waste water treatment 58.0 kg58.0 kg