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Process Data set: Polymer Aluminum Electrolytic Capacitors (PAEC) Production ; Polymer Aluminum Electrolytic Capacitors (PAEC)>2cm ; ; Primary Aluminum Ingots (en) en zh

Key Data Set Information
Location CN
Reference year 2022
Name
Polymer Aluminum Electrolytic Capacitors (PAEC) Production ; Polymer Aluminum Electrolytic Capacitors (PAEC)>2cm ; ; Primary Aluminum Ingots
Use advice for data set The inventory data provided within this dataset originates from various stages of the production process for three types of Aluminum Electrolytic Capacitors (AECs) including LAECs, PAECs, and PHAECs. Users should consider the specific manufacturing differences, especially in the repair conditions of Al2O3 dielectric films and the introduction of conductive polymers. The dataset is based on data from the year 2016 sourced from the Gabi database and information from the investigated manufacturers. For the most accurate impact assessment, users should follow the detailed Life Cycle Inventory (LCI) data and methodologies provided in the supporting documents (Supporting Info B, Sheets 5–7 for inventory data and Sheet 2 for unit impact), ensuring appropriate application in LCA context. If different years or production technologies are used in the assessment, adjustments to reflect technology and energy consumption progress should be considered.
Technical purpose of product or process This dataset provides an overview of the production process of Polymer Aluminum Electrolytic Capacitors (PAECs), which are primarily used in electronic devices for energy storage and filtering applications. These capacitors, specifically those greater than 2cm in size, are manufactured using high-purity aluminum ingots and various processes such as smelting, casting, rolling, annealing, etching, and coating to produce anode and cathode foils. The capacitors are suitable for applications where repair of dielectrics is carried out without using an electrolyte during the aging process and where conductive polymers such as PEDOT are introduced between the foils.
Classification
Class name : Hierarchy level
  • ILCD: Materials production / Metals and semimetals
General comment on data set 聚合物铝电解电容器 (PAEC) 生产阶段 ; 25V 150uf
Copyright No
Owner of data set
Quantitative reference
Reference flow(s)
Time representativeness
Time representativeness description Literature published on 2022-11-15 in the literature The reference year of the elementary data (alumminum ingots, separator paper, tansport, electricity, and water) is around 2016 and qcruired from the Gabi database (Version: 10.6.1.35)
Technological representativeness
Technology description including background system The manufacturing stage of the AECs is divided into several sub-stages in this study based on the actual fabrication segmentation in the AEC industry. First, the high-purity aluminum ingots will be smelt, cast, rolled, and annealed into the aluminum foil with a thickness of about 10–100 μm. Then, anode foil and cathode foil for the AECs will be fabricated, respectively. The same manufacturing processes are applied toward anode foil in three types of AECs. The aluminum blank foil will be etched by the weak acids to increase the superficial area of the foil, and the electrochemical reaction can further form the dielectric (Al2O3). But cathode foil of three types of AECs varies in structure and manufacturing processes due to the differences in electrolytes. The cathode foil of LAECs is made by the etched process, while the cathode foil of PAEC is made by the carbon coating process after the etched process. In PHAECs, when liquid-state electrolyte and solid-state polymer are used simultaneously, the carbon-coated cathode aluminum foil of the PAECs is also replaced by the aluminum foil with TiO2 film to overcome the potential problems on capacitor cycling life. After obtaining the anode and cathode foil, the AECs can be manufactured, assembled, and packed. Besides, there are some differences in the AEC fabrication sub-stage. The specific processes of the three types of AECs are shown in Fig. 2. In detail, the differences in manufacturing processes among the three types of AECs are mainly due to the change of repair conditions of the capacitor dielectric (Al2O3 film) and the introduction of conductive polymer. On the one hand, PAECs and PHAECs cannot use the electrolyte to repair the dielectric layer in the aging process like LAECs, so an additional forming solution is required to perform forming process, which adds extra manufacturing steps. On the other hand, the conductive polymer needs to be effectively introduced into the middle of anode and cathode foils. The conductive polymer (PEDOT) in PAECs is formed by the polymerization reaction of EDOT and oxidizing agents in the capacitor manufacturing process, while the conductive polymer (PEDOT:PSS) in PHAEC is introduced into the capacitors by the dispersive solution. The collected inventory data of LAECs, PAECs, and PHAECs by the FU are summarized in Table 2. The details of the inventory data are available in Sheets 5–7 of Supporting Info B.
Flow diagram(s) or picture(s)
  • QL21bJIXBohvCAxPv8tcCZndn9b.png Image
LCI method and allocation
Type of data set Unit process, single operation
Deviation from LCI method principle / explanations None
Deviation from modelling constants / explanations None
Data sources, treatment and representativeness
Deviation from data cut-off and completeness principles / explanations None
Data selection and combination principles The material information and performance parameters of the three types of AECs are from the investigated manufacturer. Moreover, through the field research of several factories in the AEC industry, the original data on aluminum blank foil fabrication (made from aluminum ingots), anode/cathode foil fabrication (made from aluminum blank foil), and capacitor fabrication were obtained. Due to technical confidentiality, the LCI data of the fabrication of the cathode foil for PHAECs cannot be obtained directly from the supplier. Therefore, the manufacturing LCI of aluminum cathode foil in PHAECs is adjusted according to the coating process data of cathode foil of PAECs, considering their similarity. In the transportation stage, the data of the main raw materials from the material origin to the capacitor manufacturer and the data of the manufactured capacitor products from the manufacturer to the customers are from the supply chain system of the manufacturer. The energy consumption in the use stage is calculated based on the physical equations and the electrical parameters of the AECs. To ensure the completeness of the analysis, the data of the end-of-life stage is obtained based on the analysis and calculation.The reference year of the elementary data is around 2016. The elementary data (i.e., aluminum ingots, separator paper, transport, electricity, and water) are acquired from the Gabi database (Version: 10.6.1.35). In addition, some background data, including 3, 4-ethylene dioxythiophene (EDOT), ammonium adipate, ammonium citrate, etc., are not available in the Gabi database. They are estimated based on the chemical reactions with the material preparation process from the existing raw materials in the Gabi database. The data on the preparation process of the dispersive solution (PEDOT:PSS, 1%wt) for PHAECs' fabrication are scaled from the lab data. The detailed LCI data of the three types of AEC and unit impact of the substance flow is provided in Sheets 5–7 and Sheet 2 of Supporting Info B.
Deviation from data selection and combination principles / explanations None
Deviation from data treatment and extrapolations principles / explanations None
Data source(s) used for this data set
Completeness
Completeness of product model No statement
Validation
Type of review
Dependent internal review
Reviewer name and institution
Data generator
Data set generator / modeller
Data entry by
Time stamp (last saved) 2024-04-30T20:23:58+08:00
Publication and ownership
UUID d1f4c022-a8b7-4744-931e-6a13f11f501a
Date of last revision 2024-05-13T14:41:10.957183+08:00
Data set version 01.00.005
Permanent data set URI https://lcadata.tiangong.world/showProcess.xhtml?uuid=d1f4c022-a8b7-4744-931e-6a13f11f501a&version=01.00.000&stock=TianGong
Owner of data set
Copyright No
License type Free of charge for all users and uses

Inputs

Type of flow Classification Flow Location Mean amount Resulting amount Minimum amount Maximum amount
Product flow
Energy carriers and technologies / Electricity 25644.960000000003 MJ25644.960000000003 MJ
General comment Electricity grid mix (China)
Product flow
Materials production / Metals and semimetals 346.0 kg346.0 kg
General comment 346=260.8(99.99% Al ingots)+85.2(99.9% Al ingots)
Product flow Materials production / Water 84947.0 kg84947.0 kg
Product flow Materials production / Other mineralic materials 37492.5 kg37492.5 kg
Product flow
Materials production / Metals and semimetals 486.8 m3486.8 m3
General comment Aluminum profile (China)
Product flow Materials production / Paper and cardboards 65.3 kg65.3 kg
Product flow
Materials production / Other materials 131.8 kg131.8 kg
General comment Rubber from Gabi database ({401c53f8-0ace-410b-9cc7-9a586f8ac2e6})
Product flow
Materials production / Metals and semimetals 2.12 kg2.12 kg
General comment substance flow is leads (Fe) but database from Gabi database is steel wire ({d3e4d4d7-66ee-4bea-b6eb-9704682a0b8a})
Product flow
Materials production / Metals and semimetals 15.94 m315.94 m3
General comment Tab (alluminium profile (China) )
Product flow
Materials production / Plastics 4.2517 kg4.2517 kg
General comment Tape(PP film ,from Gabi {7d6d2565-aeb4-4f36-a049-f715a80fe954})
Product flow
Materials production / Inorganic chemicals 71.9654 m371.9654 m3
General comment H3PO4
Product flow
Materials production / Inorganic chemicals 12.7679 kg12.7679 kg
General comment HBO3
Product flow
Materials production / Inorganic chemicals 97.4099 kg97.4099 kg
General comment HCl (31%)
Product flow
Materials production / Inorganic chemicals 107.9427 kg107.9427 kg
General comment NaOH (30%)
Product flow
Materials production / Inorganic chemicals 580.5631 kg580.5631 kg
General comment H2SO4 (98%)
Product flow
Materials production / Inorganic chemicals 29.223 kg29.223 kg
General comment HNO3 (98%)
Product flow
Materials production / Organic chemicals 8.9016 kg8.9016 kg
General comment Rolling oil
Product flow
Materials production / Inorganic chemicals 24.5909 m324.5909 m3
General comment Ammonium citrate
Product flow
Emissions / Inorganic covalent compounds 6.7447 kg6.7447 kg
General comment Ammonium pentaborate
Product flow
Materials production / Inorganic chemicals 34.3393 m334.3393 m3
General comment Ammonium adipate
Product flow
Materials production / Inorganic chemicals 1.124 m31.124 m3
General comment NH4H2PO4
Product flow
Materials production / Metals and semimetals 10.9643 m310.9643 m3
General comment Carbon coating paste
Product flow
Materials production / Organic chemicals 14.025 kg14.025 kg
General comment EDOT
Product flow
Emissions / Metal and semimetal elements and ions 35.3129 kg35.3129 kg
General comment Iron (III) p-toluene sulfonate hexahydrate
Product flow
Materials production / Organic chemicals 28.8924 kg28.8924 kg
General comment N-butanol

Outputs

Type of flow Classification Flow Location Mean amount Resulting amount Minimum amount Maximum amount
Product flow
Emissions / Inorganic covalent compounds 9.0494 kg9.0494 kg
General comment AlPO4 (by-product)4
Waste flow
Wastes / Production residues 62925.1701 Item(s)62925.1701 Item(s)
General comment Capacitors (waste)
Waste flow
Wastes / Waste water 73437.4183 m373437.4183 m3
General comment Waste water
Product flow
Energy carriers and technologies / Crude oil based fuels 8.5165 kg8.5165 kg
General comment Sludge
Product flow
Materials production / Metals and semimetals 23.7393 m323.7393 m3
General comment Al scraps
Elementary flow
Emissions / Emissions to water / Emissions to water, unspecified 3.2703 kg3.2703 kg
General comment COD
Product flow
Systems / Electrics and electronics 1000000.0 Item(s)1000000.0 Item(s)
General comment capacitors (product)