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Process Data set: LIB Hydrometallurgy--organic acid leaching(Process E) (en) en zh

Key Data Set Information
Location CN
Reference year 2013
Name
LIB Hydrometallurgy--organic acid leaching(Process E)
Use advice for data set Users of this Life Cycle Assessment (LCA) data set should note that the input-output of Process E is derived from averaged literature review data representing a 'cradle-to-grave' approach within the time frame of 2013-2017. The data excludes considerations of plastic and metal casing recycling or treatment, as well as labor and factory construction costs and their environmental impact. Additionally, users should exercise caution when applying this EU-based data in the Chinese context, as it may not completely align with the industry-specific conditions in China. Modifications using official Chinese data, industry reports, and information from trade associations have been estimated to reflect the data from Chinese stakeholders better. For timeliness, reference the data from the most recent four-year average period available, specifically 2013-2016. Functional unit (FU) reference is based on 100 kg of typical LIB electrode material.
Technical purpose of product or process The hydrometallurgical organic acid leaching process (Process E) uses weak acids such as acetic acid and citric acid along with a reducing agent as the leaching solution. The weak acid selectively leaches valuable metals by reacting with the active materials of the positive electrode while not affecting the aluminum foil collector. This allows for selective recovery and reprocessing of the electrode materials by adjusting the pH and adding metal salts to cause co-precipitation of the valuable metals. This process is applicable in the battery recycling industry, particularly for the regeneration of Lithium-Ion Battery (LIB) electrode materials.
Classification
Class name : Hierarchy level
  • ILCD: End-of-life treatment / Material recycling
General comment on data set Weak acid (e.g. acetic acid, citric acid, etc.) and reducing agent are used as leaching agent, and the weak acid can react with positive electrode active material without reacting with the aluminum foil of collector, so as to realize selective leaching of valuable metal, and the product can realize electrode active material reproduction by adjusting pH, adding metal salt and so on, so as to cause co-precipitation of valuable metal.
Copyright No
Owner of data set
Quantitative reference
Reference flow(s)
Functional Unit FU is a typical type of LIB electrode material of 100 kg
Time representativeness
Data set valid until 2017
Time representativeness description Data source: 2013-2017
Technological representativeness
Flow diagram(s) or picture(s)
  • QuELbmhO5oFDHgxYwwkclX3En8f.png Image
LCI method and allocation
Type of data set Unit process, single operation
Deviation from LCI method principle / explanations None
Deviation from modelling constants / explanations None
Data sources, treatment and representativeness
Deviation from data cut-off and completeness principles / explanations None
Data selection and combination principles The input-output of the process comes from the average results of the data reported in the literature review, reflecting the representative process from "tomb" to "cradle". This study does not consider the recycling or treatment of plastic and metal shells, and labor costs, factory construction costs, and their impact on the environment are also not included in this analysis.
Deviation from data selection and combination principles / explanations None
Data treatment and extrapolations principles It is worth noting that the EU's data is not specific to a specific industry, and some import and export data and recycling information are not suitable for China's situation. Therefore, the improved CRMs evaluation method also combines official Chinese data, literature reports, and data from other interest groups such as trade/industry associations to conduct the best estimation of data from major LIB manufacturers, recycling companies, official management agencies in China, and other stakeholders. In terms of data timeliness, the reference period used in the evaluation of CRMs is based on the latest 4-year average (i.e. 2013-2016).
Deviation from data treatment and extrapolations principles / explanations None
Data source(s) used for this data set
Completeness
Completeness of product model No statement
Validation
Type of review
Dependent internal review
Reviewer name and institution
Data generator
Data set generator / modeller
Data entry by
Time stamp (last saved) 2024-02-04T12:52:34+08:00
Publication and ownership
UUID 256a84ce-b47a-493b-8ade-554b70e9cc6c
Date of last revision 2024-05-13T14:56:16.287482+08:00
Data set version 01.00.005
Permanent data set URI https://lcadata.tiangong.world/showProcess.xhtml?uuid=256a84ce-b47a-493b-8ade-554b70e9cc6c&version=01.00.000&stock=TianGong
Owner of data set
Copyright No
License type Free of charge for all users and uses

Inputs

Type of flow Classification Flow Location Mean amount Resulting amount Minimum amount Maximum amount
Product flow
Materials production / Other materials 100.0 kg100.0 kg
General comment Electrode paste
Product flow Materials production / Organic chemicals 93.3 kg93.3 kg
Product flow Materials production / Inorganic chemicals 17.0 kg17.0 kg
Product flow Materials production / Inorganic chemicals 3.0 kg3.0 kg
Product flow Materials production / Inorganic chemicals 10.6 kg10.6 kg
Elementary flow Resources / Resources from water / Renewable material resources from water 380.0 m3380.0 m3
Product flow
Materials production / Other mineralic materials 1.4 kg1.4 kg
General comment Natural gas:8500 kCal
Product flow Energy carriers and technologies / Electricity 64.08 MJ64.08 MJ

Outputs

Type of flow Classification Flow Location Mean amount Resulting amount Minimum amount Maximum amount
Product flow Materials production / Inorganic chemicals 10.5 kg10.5 kg
Product flow
Materials production / Inorganic chemicals 17.6 kg17.6 kg
General comment Graphite powder
Product flow Materials production / Other materials 5.4 kg5.4 kg
Product flow
Materials production / Other materials 14.0 kg14.0 kg
General comment Ni salt、metal
Product flow
Materials production / Other materials 15.0 kg15.0 kg
General comment Co salt、metal
Product flow
Materials production / Other materials 12.0 kg12.0 kg
General comment Mn salt、metal
Product flow Materials production / Other materials 10.0 kg10.0 kg
Waste flow Wastes 4.8 kg4.8 kg
Elementary flow
Emissions / Emissions to air / Emissions to air, unspecified 9.0 kg9.0 kg
General comment The original text does not distinguish between bio and fossil, and according to experts, it is fossil here
Product flow End-of-life treatment / Waste water treatment 360.0 kg360.0 kg