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Process Data set: End-of-life LFP batteryAdvanced hydrometallurgy process (en) en zh

Key Data Set Information
Location CN
Reference year 2020
Name
End-of-life LFP batteryAdvanced hydrometallurgy process
Use advice for data set The life cycle assessment data pertaining to the advanced hydrometallurgy process for LFP batteries should be used carefully, considering the unique aspects of the recycling process. The functional unit for this data set is 1 kWh of battery capacity. Users need to ensure that comparisons or assessments are made on a similar basis and scale. Attention should be given to methodological choices, such as the allocation of environmental impacts between the recycled product and the original waste stream. It is important to note that the data come from multiple papers and may contain variability that could affect the outcome of the analysis.
Technical purpose of product or process The advanced hydrometallurgy process described is specifically used for the recovery of materials from waste lithium iron phosphate (LFP) batteries. The end product is battery-grade lithium carbonate, which is a critical raw material for the manufacturing of new lithium iron phosphate batteries, as well as other lithium-based chemical products.
Classification
Class name : Hierarchy level
  • ILCD: End-of-life treatment / Material recycling
General comment on data set Before adopting wet process for material recovery, the waste lithium iron phosphate batteries are safely discharged, disassembled, pyrolyzed, mechanically crushed, and sorted to get powdered lithium-containing waste. Lithium-containing material is added to leaching solvent for leaching, filtered and separated to get lithium-containing solution, added to the purification agent for reaction, filtered, concentrated, and under certain reaction conditions, added to the precipitation agent fully reacted to crystallization and precipitation, filtered, washed and dried to get battery-grade lithium carbonate.
Copyright No
Owner of data set
Quantitative reference
Reference flow(s)
Functional Unit using 1 kWh as the functionalunit
Technological representativeness
Technology description including background system Leaching: During the leaching process, the solid-liquid ratio of the selected electrode materials for smelting and the leaching solution should be controlled within the appropriate range, and should be stirred evenly and reacted adequately.Impurity removal: The impurity removal process should be based on the premise of not introducing excess impurities, combined with precipitation and extraction methods to ensure that the impurity elements are reasonably removed, and reduce the loss of nickel, cobalt, manganese, lithium and other elements.Purification: Should be purified according to the characteristics of metal elements, select the appropriate extractant, under certain extraction conditions, after multiple extraction, to obtain a high-purity target metal solution, such as nickel, cobalt, manganese solution or lithium solution.Material synthesis: Material synthesis is the process of converting metal purification liquid into positive electrode materials, precursors and other battery materials. The products synthesized by the material should meet the national standards or industry standards of the relevant products, nickel diamond lithium manganese oxide should meet the requirements of YS/T798, nickel cobalt manganese hydroxide should meet the requirements of GB/T26300.
Flow diagram(s) or picture(s)
  • MYcfbEAkDozT5xxEpSEcKZGUnnb.png Image
LCI method and allocation
Type of data set Unit process, single operation
Deviation from LCI method principle / explanations None
Deviation from modelling constants / explanations None
Data sources, treatment and representativeness
Deviation from data cut-off and completeness principles / explanations None
Data selection and combination principles The data come from multiple papers and are difficult to distinguish.
Deviation from data selection and combination principles / explanations None
Deviation from data treatment and extrapolations principles / explanations None
Data source(s) used for this data set
Completeness
Completeness of product model No statement
Validation
Type of review
Dependent internal review
Reviewer name and institution
Data generator
Data set generator / modeller
Data entry by
Time stamp (last saved) 2024-04-11T16:11:53+08:00
Publication and ownership
UUID 562444aa-b91d-4865-8ecb-8758777ae34d
Date of last revision 2024-05-13T14:55:57.709118+08:00
Data set version 01.00.005
Permanent data set URI https://lcadata.tiangong.world/showProcess.xhtml?uuid=562444aa-b91d-4865-8ecb-8758777ae34d&version=01.00.000&stock=TianGong
Owner of data set
Copyright No
License type Free of charge for all users and uses

Inputs

Type of flow Classification Flow Location Mean amount Resulting amount Minimum amount Maximum amount
Product flow
Materials production / Inorganic chemicals 2.04 kg2.04 kg
General comment Sodium hydroxide, production mix/EU-28
Product flow
Materials production / Inorganic chemicals 0.29 kg0.29 kg
General comment Hydrogen peroxide production mix/DE
Product flow
Materials production / Organic chemicals 14.38 kg14.38 kg
General comment Citric acid,New process based on GREET/CN
Product flow
Materials production / Inorganic chemicals 0.9 kg0.9 kg
General comment Soda (Na2CO3)
Product flow Energy carriers and technologies / Electricity 4.58 MJ4.58 MJ
Product flow Materials production / Other mineralic materials 11.79 kg11.79 kg
Product flow End-of-life treatment / Material recycling 3.6 kg3.6 kg

Outputs

Type of flow Classification Flow Location Mean amount Resulting amount Minimum amount Maximum amount
Elementary flow
Resources / Resources from air / Renewable material resources from air 0.16 kg0.16 kg
General comment The original text does not distinguish between bio and fossil, and according to experts, it is fossil here
Elementary flow Resources / Resources from ground / Non-renewable element resources from ground 0.8 kg0.8 kg
Elementary flow Resources / Resources from ground / Non-renewable element resources from ground 1.01 kg1.01 kg
Elementary flow Resources / Resources from ground / Non-renewable element resources from ground 0.92 kg0.92 kg
Product flow
Materials production / Inorganic chemicals 0.63 kg0.63 kg
General comment Li2CO3